Molecular weights | |||
---|---|---|---|
NH4ClO4 | NH4 | NH4OH | NaClO4 |
117.5 | 18 | 35 | 122.5 |
I asked a guy the following: Can you make Ammonium Perchlorate by bubbling ammonia gas into Sodium Perchlorate solution? NH3 + NaClO4 + H2O <===> NH4ClO4 (ppt out) + Na0H I have never seen it mentioned in the literature anywhere. Will adding Ammonium Hydroxide (same as above really) work either? ------------------------ ------------------------ The problem is that the Ammonia is a gas and is therefore free to escape while the NaOH has nowhere to go and will tend to favour the reverse reaction (especially at higher temperature): NH4ClO4 + NaOH -> NaClO4 + H2O + NH3 You could try to take advantage of the much lower solubility of NH4ClO4 in water, If you start with a concentrated solution of NaClO4 at 0 degrees or even a bit lower, bubbling in Ammonia gas (under pressure if possible) might cause NH4ClO4 to precipitate/crystallise since it is much less soluble than NaClO4. The low temperature and pressure will both help to reduce the loss of Ammonia gas, thus favouring the forward (desired) reaction. The NH4ClO4 would then have to be washed free of NaOH with aqua Ammonia to prevent the residual NaOH from displacing Ammonium ions in the Ammonium Perchlorate and contaminating the product.
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