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Potassium Chlorate is not hygroscopic
and has no known hydrates.
Potassium Chlorate can be made similarly to Sodium
Chlorate. Since Potassium Chlorate is much less soluble than Na Chlorate the K
Chlorate will crystallise out of the cell electrolyte as you run the cell. If you
are using carbons as Anodes the Graphite will be difficult to separate out of
the solid product and you will have to re-dissolve it in order to filter out the
Graphite. If using Lead Dioxide there will be a small amount of brown Lead
Dioxide on the bottom of the cell with the solid Chlorate and if you wish to
remove it you will have to re dissolve the Chlorate and filter. This will take
a lot of water as the K Chlorate is not very soluble and if you try to use very hot
water you will get the K Chlorate crystallising out in the filter.
Chlorate is by far the most popular Chlorate for the amateur to make as it is dangerous to use Sodium Chlorate for Pyro stuff.
If you keep your cell clean, use a MMO (DSA), or Pt anode and a non corroding
Cathode (proper type of SS or Ti) you will be able to harvest almost pure K
Chlorate from your cell at regular intervals. It should be given a wash
using cold water to get rid of any KCl that is clinging to it. Washings should be returned to the cell so that nothing is wasted.
can be obtained as a fertilizer, it is called Muriate of Potash. It will have
50% (approx) K written on the bag. In the USA where % K is given in a
different way it will have a different figure. Very often it is 49%K and a recrystallization may be in order to purify the KCl.
Another possible source of KCl
is with the people who sell equipment for softening water. Sodium Chloride is
usually used in theses devices but some people object to having any Sodium ion
in their drinking water so they need to use Potassium Chloride instead, so you
may be able to get a bag of Potassium Chloride in the same place as where they
supply the NaCl for the water softeners
Run timeYou should start off your K cell with about 340g of K Chloride (approx.)
per litre of water (saturated solution). When running
the cell you may add water or KCl solution to top it up if evaporation allows. A similar modification,
as per the Na cell, should be made to the run time of the K cell if you are
using KCl solution to top up the cell.
The run time for a K Chlorate cell
can be calculated by simply dividing the figure's in the table (in the run time
section for Na Chlorate) by 1.27 and using the resulting figure as per usual in
the formula, or use the program.
At the end of the run you will have a ppt of Chlorate on the bottom of the
Remove the Chlorate, and add 0.61 grams KCl for every gram K Chlorate
removed from cell and top up with water if necessary. You will now be back
(approx.) to the conditions at the start of the run. The run time will be the
same as it was the first time. You will probably have to recrystallize your crop
of K Chlorate to clean it up from Lead Dioxide or Graphite. If using MMO (DSA) and a
non corroding cathode you can use after a singe wash to remove Chloride.
Potassium Chlorate from Sodium ChloratePotassium Chlorate can also be
made by adding KCl solution to Sodium Chlorate solution (so called double
decomposition). The Potassium Chlorate will ppt out as it is the least soluble
of all the components in the solution.
If you make Sodium Chlorate first and
then make Potassium Chlorate by adding KCl, you can get rid of Lead Dioxide
powder by letting the Sodium Chlorate cell settle for a day and then decanting
off the Sodium Chlorate. This saves you the bother of filtering. You could
probably get rid of the Graphite by the same method (if you are using a Graphite
Anode) but you would have to let the cell settle for more than a day (give it a boil to get rid of dissolved gasses) and the
decanting would have to be done carefully. When the decanting is done you will
have a clear liquid containing Sodium Chlorate + NaCl that can be used to make
your K Chlorate.
The amount of KCl to add to the Sodium Chlorate will depend on the amount of
Sodium Chlorate that you have in solution. You need the same amount of moles of
KCl as there are moles NaClO3 if you want to get as much
KClO3 as possible. For every gram NaClO3 you will
need 74.5/106.5 = 0.699 grams KCl. It is difficult to know how much
NaClO3 you have in the solution if you have not started with
solid NaClO3 and dissolved it in the water.
The whole thing can be simplified if you are going to make more Na Chlorate
in order to make more K Chlorate. If you simply estimate the amount of Sodium
Chlorate in the solution and add the appropriate amount of KCl. You can do this
when the solution is cold. Keep adding the KCl slowly with stirring until you
are getting no more precipitation of KClO3. Then stop adding the
KCl and filter out the KClO3. You can then start up the Sodium
Chlorate cell again by using the solution that you filtered. There will now be
enough Sodium Chloride in the cell for electrolysed to begin. There will be some
K Chlorate dissolved in the cell but it will not matter. You will get it out the
next time around. The run time will be similar to the first time around, or
slightly shorter (5 - 10%).
|Some useful data|
Graph above shows the solubility of some K Compounds.
tables for a collection of data regarding solubility’s of K Chlorate + K
Chloride and K Chlorate + Na Chloride.
Some patents on K Chlorate production are, US 4339312 and US 2287061
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